721 research outputs found

    Continuous Uniform Finite Time Stabilization of Planar Controllable Systems

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    Continuous homogeneous controllers are utilized in a full state feedback setting for the uniform finite time stabilization of a perturbed double integrator in the presence of uniformly decaying piecewise continuous disturbances. Semiglobal strong C1\mathcal{C}^1 Lyapunov functions are identified to establish uniform asymptotic stability of the closed-loop planar system. Uniform finite time stability is then proved by extending the homogeneity principle of discontinuous systems to the continuous case with uniformly decaying piecewise continuous nonhomogeneous disturbances. A finite upper bound on the settling time is also computed. The results extend the existing literature on homogeneity and finite time stability by both presenting uniform finite time stabilization and dealing with a broader class of nonhomogeneous disturbances for planar controllable systems while also proposing a new class of homogeneous continuous controllers

    Achieving provider engagement: providers' perceptions of implementing and delivering integrated care

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    The literature on integrated care is limited with respect to practical learning and experience. Although some attention has been paid to organizational processes and structures, not enough is paid to people, relationships, and the importance of these in bringing about integration. Little is known, for example, about provider engagement in the organizational change process, how to obtain and maintain it, and how it is demonstrated in the delivery of integrated care. Based on qualitative data from the evaluation of a large-scale integrated care initiative in London, United Kingdom, we explored the role of provider engagement in effective integration of services. Using thematic analysis, we identified an evolving engagement narrative with three distinct phases: enthusiasm, antipathy, and ambivalence, and argue that health care managers need to be aware of the impact of professional engagement to succeed in advancing the integrated care agenda

    Extending standard testing period in honeybees to predict lifespan impacts of pesticides and heavy metals using dynamic energy budget modelling

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    Concern over reported honeybee (Apis mellifera spp.) losses has highlighted chemical exposure as a risk. Current laboratory oral toxicity tests in A. mellifera spp. use short-term, maximum 96 hour, exposures which may not necessarily account for chronic and cumulative toxicity. Here, we use extended 240 hour (10 day) exposures to examine seven agrochemicals and trace environmental pollutant toxicities for adult honeybees. Data were used to parameterise a dynamic energy budget model (DEBtox) to further examine potential survival effects up to 30 day and 90 day summer and winter worker lifespans. Honeybees were most sensitive to insecticides (clothianidin > dimethoate ≫ tau-fluvalinate), then trace metals/metalloids (cadmium, arsenic), followed by the fungicide propiconazole and herbicide 2,4-dichlorophenoxyacetic acid (2,4-D). LC50s calculated from DEBtox parameters indicated a 27 fold change comparing exposure from 48 to 720 hours (summer worker lifespan) for cadmium, as the most time-dependent chemical as driven by slow toxicokinetics. Clothianidin and dimethoate exhibited more rapid toxicokinetics with 48 to 720 hour LC50s changes of <4 fold. As effects from long-term exposure may exceed those measured in short-term tests, future regulatory tests should extend to 96 hours as standard, with extension to 240 hour exposures further improving realism

    Digital storytelling and Co-creative Media: The role of community arts and media in propagating and coordinating population-wide creative practice

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    How is creative expression and communication extended among whole populations? What is the social and cultural value of this activity? What roles do formal agencies, community-based organisations and content producer networks play? Specifically, how do participatory media and arts projects and networks contribute to building this capacity in the contemporary communications environment

    Emerging and legacy plasticisers in coastal and estuarine environments: a review

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    The occurrence of plastic waste in the environment is an emerging and ongoing concern. In addition to the physical impacts of macroplastics and microplastics on organisms, the chemical effects of plastic additives such as plasticisers have also received increasing attention. Research concerning plasticiser pollution in estuaries and coastal environments has been a particular focus, as these environments are the primary entry point for anthropogenic contaminants into the wider marine environment. Additionally, the conditions in estuarine environments favour the sedimentation of suspended particulate matter, with which plasticisers are strongly associated. Hence, estuary systems may be where some of the highest concentrations of these pollutants are seen in freshwater and marine environments. Recent studies have confirmed emerging plasticisers and phthalates as pollutants in estuaries, with the relative abundance of these compounds controlled primarily by patterns of use, source intensity, and fate. Plasticiser profiles are typically dominated by mid-high molecular weight compounds such as DnBP, DiBP, and DEHP. Plasticisers may be taken up by estuarine and marine organisms, and some phthalates can cause negative impacts in marine organisms, although further research is required to assess the impacts of emerging plasticisers. This review provides an overview of the processes controlling the release and partitioning of emerging and legacy plasticisers in aqueous environments, in addition to the sources of plasticisers in estuarine and coastal environments. This is followed by a quantitative analysis and discussion of literature concerning the (co-)occurrence and concentrations of emerging plasticisers and phthalates in these environments. We end this review with a discussion the fate (degradation and uptake by biota) of these compounds, in addition to identification of knowledge gaps and recommendations for future research

    Co-occurrence of macroplastics, microplastics, and legacy and emerging plasticisers in UK soils

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    Despite a theoretical link between plastic and plasticiser occurrence in the terrestrial environment, there are few empirical studies of the relationship between these contaminants in soils. We carried out a field study to assess the cooccurrence of plastic waste, and legacy and emerging plasticisers in UK soils (n = 19) from various land uses (woodlands, urban roadsides, urban parklands, landfill-associated). Surface plastics and soil microplastics were quantified and characterised using ATR-FTIR and μ-FTIR. Eight legacy (phthalate) and three emerging (adipate, citrate, trimellitate) plasticisers were quantified using GC–MS. Surface plastics were found at higher prevalence at landfillassociated and urban roadside sites, with levels significantly (2 orders of magnitude) greater than in woodlands. Microplastics were detected in landfill-associated (mean 12.3 particles g−1 dw), urban roadside (17.3 particles g−1dw) and urban parkland (15.7 particles g−1 dw) soils, but not in woodland soils. The most commonly detected polymers were polyethene, polypropene and polystyrene. Mean ∑plasticiser concentration in urban roadside soils (3111 ng g−1 dw) was significantly higher than in woodlands (134 ng g−1 dw). No significant difference was found between landfill-associated (318 ng g−1 dw) and urban parkland (193 ng g−1 dw) soils and woodlands. Di-n-butyl phthalate (94.7% detection frequency) and the emerging plasticiser trioctyl trimellitate (89.5%) were the most commonly detected plasticisers, with diethylhexyl phthalate (493 ng g−1 dw) and di-iso-decyl phthalate (96.7 ng g−1 dw) present at the highest concentrations. ∑plasticiser concentrations were significantly correlated with surface plastic (R2 = 0.23), but not with soil microplastic concentrations. Whilst plastic litter seems a fundamental source of plasticisers in soils, mechanisms such as airborne transport from source areas may be as important. Based on the data from this study, phthalates remain the dominant plasticisers in soils, but emerging plasticisers are already widespread, as reflected by their presence in all land uses studied
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